Determination of water content using mass spectrometry

Mass spectrometer is used to measure small quantities of water present in different materials. System has been applied in measuring water and gases desorbed from microcircuitry insulation, can also be used with foods, polymeric materials, and organic solvents

Dynamic delta method for trace gas analysis

Method has been developed in which measurements are made only over viscous flow range, eliminating fractionation before the molecular leak and problems due to surface elution

Inverting a Supernova: Neutrino Mixing, Temperatures and Binding Energy

We show that the temperatures of the emergent non-electron neutrinos and the binding energy released by a galactic Type II supernova are determinable, assuming the Large Mixing Angle (LMA) solution is correct, from observations at the Sudbury Neutrino Observatory (SNO) and at Super-Kamiokande (SK). If the neutrino mass hierarchy is inverted, either a lower or upper bound can be placed on the neutrino mixing angle $\theta_{13}$, and the hierarchy can be deduced for adiabatic transitions. For the normal hierarchy, neither can $\theta_{13}$ be constrained nor can the hierarchy be determined. Our conclusions are qualitatively unchanged for the proposed Hyper-Kamiokande detector.Comment: Following astro-ph/0208035, we adopt electron and non-electron neutrino spectra with very small differences. Conclusions change

Phonon entropy of alloying and ordering of Cu-Au

Inelastic neutron scattering spectra were measured with a time-of-flight spectrometer on six disordered Cu-Au alloys at 300 K. The neutron-weighted phonon density of states was obtained from a conventional analysis of these spectra. Several methods were developed to account for this neutron weighting and obtain the phonon entropy of the disordered alloys. The phonon entropies of formation of disordered fcc Cu-Au alloys obtained in this way were generally mutually consistent, and were also consistent with predictions from a cluster approximation obtained from ab-initio calculations by Ozolin[underaccent cedilla [below] s-breve, Wolverton, and Zunger. We estimate a phonon entropy of disordering of 0.15±0.05kB/atom in Cu3Au at 300 K. A resonance mode associated with the motions of the heavy Au atoms in the Cu-rich alloys was observed at 9 meV. An analysis of the resonance mode provided a check on the partial phonon entropy of Au atoms

Correspondence between one- and two-equation models for solute\ud transport in two-region heterogeneous porous media

In this work, we study the transient behavior of upscaled models for solute transport in two-region porous media. We focus on the following three models: (1) a time non-local, two-equation model (2eq-nlt). This model does not rely on time constraints and, therefore, is particularly useful in the short-time regime, when the time scale of interest (t) is smaller than the characteristic time (T1) for the relaxation of the effective macroscale parameters (i.e., when t ≤ T1); (2) a time local, two-equation model (2eq). This model can be adopted when (t) is significantly larger than (T1) (i.e., when t » T1); and (3) a one-equation, time-asymptotic formulation (1eq∞). This model can be adopted when (t) is significantly larger than the time scale (T2) associated with exchange processes between the two regions (i.e., when t » T2). In order to obtain some physical insight into this transient behavior, we combine a theoretical approach based on the analysis of spatial moments with numerical and analytical results in simple cases. The main result of this paper is to show that there is weak long-time convergence of the solution of (2eq) toward the solution of (1eq∞) in terms of standardized moments but, interestingly, not in terms of centered moments. Physically, our interpretation of this result is that the spreading of the solute is dominating higher order non-zero perturbations in the asymptotic regime

Performance evaluation of a six-axis generalized force-reflecting teleoperator

Work in real-time distributed computation and control has culminated in a prototype force-reflecting telemanipulation system having a dissimilar master (cable-driven, force-reflecting hand controller) and a slave (PUMA 560 robot with custom controller), an extremely high sampling rate (1000 Hz), and a low loop computation delay (5 msec). In a series of experiments with this system and five trained test operators covering over 100 hours of teleoperation, performance was measured in a series of generic and application-driven tasks with and without force feedback, and with control shared between teleoperation and local sensor referenced control. Measurements defining task performance included 100-Hz recording of six-axis force/torque information from the slave manipulator wrist, task completion time, and visual observation of predefined task errors. The task consisted of high precision peg-in-hole insertion, electrical connectors, velcro attach-de-attach, and a twist-lock multi-pin connector. Each task was repeated three times under several operating conditions: normal bilateral telemanipulation, forward position control without force feedback, and shared control. In shared control, orientation was locally servo controlled to comply with applied torques, while translation was under operator control. All performance measures improved as capability was added along a spectrum of capabilities ranging from pure position control through force-reflecting teleoperation and shared control. Performance was optimal for the bare-handed operator

Marginal states of the resistive tearing mode with flow in cylindrical geometry

The linear stability of tearing modes in a cylindrical plasma subject to a sub-Alfvénic equilibrium shear flow along the equilibrium magnetic field is considered. The equations in the resistive boundary layer at the rational surface are solved numerically using a Fourier transform combined with a finite-element approach. The behaviour of the growth rate as a function of the flow and the various parameters (including a perpendicular fluid viscosity) is obtained. Marginal stability curves showing the dependence of the familiar matching parameter Δ' with flow and shear are also given

Project management in the Apollo program Interim report

Project management in Apollo progra

On-line mass spectrometric monitoring of the polymerization of a phenolic-resin-based material

Polymerization of phenolic-resin-based materials requires elevated temperatures. The low thermal conductivity of these materials has led to the use of dielectric heating techniques in lieu of standard convection oven heating to obtain a satisfactory cure. The curing rate and therefore the quality of the cured material depends on the heating rate and maximum temperature attained, parameters which are extremely difficult to measure in dielectric heating units. The dielectric curing of these materials was monitored by using a mass spectrometer to measure the partial pressure of phenol in the gas evolved during polymerization. The resulting plots of phenol partial pressure as a function of time have a characteristic shape, and these may be used to indicate the attainment of complete curing. The validity of the mass spectrometric technique was confirmed by chemical analysis of the polymerized samples